Fluoroacrylate-bound fluorous-phase soluble hydrogenation catalysts

被引：39

作者：

Bergbreiter, DE ^{[1
]}

Franchina, JG ^{[1
]}

Case, BL ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 03期

关键词：

D O I：

10.1021/ol991352h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Fluoroacrylate polymer-bound hydrogenation catalysts are described, N-Acryloxysuccinimide-containing fluoroacrylate polymers were converted into phosphine ligands and subsequently into analogues of Wilkinson's catalyst by amidation of N-acryloxysuccinimide active ester residues and Rh exchange. The resulting catalysts have excellent activity and can be reused following fluorous biphasic liquid/liquid separation and extraction.

引用

页码：393 / 395

页数：3

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← 1 2 3 4 →