Distribution of crown hexameric procyanidin and its tetrameric and pentameric congeners in red and white wines

被引:23
作者
Longo, Edoardo [1 ,2 ]
Rossetti, Fabrizio [3 ]
Jouin, Alicia [4 ]
Teissedre, Pierre-Louis [4 ]
Jourdes, Michael [4 ]
Boselli, Emanuele [1 ,2 ]
机构
[1] Free Univ Bozen Bolzano, Fac Sci & Technol, Piazza Univ 1, Bozen Bolzano, Italy
[2] NOITechpk Sudtirol Alto Adige, Oenolab, Via A Volta 13 B, I-39100 Bolzano, Italy
[3] Marche Polytech Univ, Dept Agr Food & Environm Sci, Via Brecce Bianche 10, I-60131 Ancona, Italy
[4] Univ Bordeaux, Unite Rech OEnol, EA 4577, USC 1366,INRA,ISVV, 210 Chemin Leysotte, F-33882 Villenave Dornon, France
关键词
Crown procyanidins; Cyclic procyanidins; High resolution mass spectrometry; Wine authenticity; Grape varieties; MASS-SPECTROMETRY; PROANTHOCYANIDINS; PIGMENTS;
D O I
10.1016/j.foodchem.2019.125125
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Nineteen red and white wines were screened for the presence of crown (oligomeric cyclic) procyanidins with 4, 5 or 6 (epi)catechin monomers by means of HPLC-HRMS/MS. For the first time, the distribution of crown procyanidins in wines obtained from several grape varieties was discussed including white wines. The ratios between crown and non-cyclic procyanidins allowed the samples to be discriminated by grape variety. The crown hexameric procyanidin was present in the red wines and absent in the white wines analyzed. The crown pentameric procyanidin was absent in Gewurztraminer. In Chardonnay and Sauvignon Blanc, the pentameric procyanidin was present only in the cyclic form. Less oxidized high quality red wines displayed a higher fraction of crown to non-cyclic procyanidins than the other wines. These compounds are proposed as potential complement markers of wine quality and authenticity.
引用
收藏
页数:9
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