Well-aligned cellulose nanofiber-reinforced polyvinyl alcohol composite film: Mechanical and optical properties

被引:85
作者
Cai, Jie [1 ,3 ]
Chen, Jingyao [3 ]
Zhang, Qian [1 ]
Lei, Miao [1 ]
He, Jingren [1 ]
Xiao, Anhong [1 ]
Ma, Chengjie [2 ]
Li, Sha [2 ]
Xiong, Hanguo [3 ]
机构
[1] Wuhan Polytech Univ, Coll Food Sci & Engn, Wuhan 430023, Peoples R China
[2] Technol Ctr Bright Dairy & Food Co Ltd, State Key Lab Dairy Biotechnol, Shanghai 200436, Peoples R China
[3] Huazhong Agr Univ, Coll Food Sci & Technol, Wuhan 430070, Peoples R China
基金
中国国家自然科学基金;
关键词
Cellulose; Nanofiber; Electrospinning; Reinforcements; Composite films; ELECTROSPUN; FIBERS; SOLVENT; MATS; POLYACRYLONITRILE; FABRICATION; BEHAVIOR; BAMBOO;
D O I
10.1016/j.carbpol.2015.12.039
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Uniaxially aligned cellulose nanofibers (CNFs), which are fabricated by electrospinning of cellulose acetate derived from bamboo cellulose (B-CA) followed by deacetylation, were used as reinforcements to make optically transparent composite films. We examined the effects of B-CA concentration and electrospinning parameters (e.g. spinning distance, and collection speed) on fiber morphology and orientation, which act on mechanical-to-optical properties of the CNFs-reinforced composites. Consequently, the resultant composite film exhibits high visible-light transmittance even with high fiber content, as well as improved mechanical properties. The understanding obtained from this study may facilitate the development of novel nanofibrous materials for various optical uses. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:238 / 245
页数:8
相关论文
共 49 条
[11]   Electrospinning of ultrafine cellulose fibers and fabrication of poly(butylene succinate) biocomposites reinforced by them [J].
Han, Seong Ok ;
Son, Won Keun ;
Youk, Ji Ho ;
Park, Won Ho .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (03) :1954-1959
[12]   Ultrafine porous fibers electrospun from cellulose triacetate [J].
Han, SO ;
Son, WK ;
Youk, JH ;
Lee, TS ;
Park, WH .
MATERIALS LETTERS, 2005, 59 (24-25) :2998-3001
[13]   Acetylation of Chitin Nanofibers and their Transparent Nanocomposite Films [J].
Ifuku, Shinsuke ;
Morooka, Shin ;
Morimoto, Minoru ;
Saimoto, Hiroyuki .
BIOMACROMOLECULES, 2010, 11 (05) :1326-1330
[14]  
Ju Y. P., 2008, J IND ENG CHEM, V4, P707
[15]   The use of carbon nanofiber electrodes prepared by electrospinning for electrochemical supercapacitors [J].
Kim, C ;
Yang, KS ;
Lee, WJ .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (11) :A397-A399
[16]  
Kim C. W., 2005, J POLYM SCI B, V43, P1613
[17]   Structural studies of electrospun cellulose nanofibers [J].
Kim, Choo-Won ;
Kim, Dae-Sik ;
Kang, Seung-Yeon ;
Marquez, Manuel ;
Joo, Yong Lak .
POLYMER, 2006, 47 (14) :5097-5107
[18]  
King RL., 1989, COMPOSITES PART APPL, V20, P172, DOI 10.1016/0010-4361(89)90651-4
[19]   Cellulose nanofibers prepared by the N-methylmorpholine-N-oxide method [J].
Kulpinski, P .
JOURNAL OF APPLIED POLYMER SCIENCE, 2005, 98 (04) :1855-1859
[20]   MECHANICAL-PROPERTIES OF BAMBOO, A NATURAL COMPOSITE [J].
LAKKAD, SC ;
PATEL, JM .
FIBRE SCIENCE & TECHNOLOGY, 1981, 14 (04) :319-322