Helium on planar and nanostructured alkali-metal surfaces

被引:19
作者
Ancilotto, F. [1 ,2 ]
Barranco, M. [3 ,4 ]
Hernandez, E. S. [5 ]
Hernando, A. [3 ,4 ]
Pi, M. [3 ,4 ]
机构
[1] Univ Padua, Dipartimento Fis G Galilei, I-35131 Padua, Italy
[2] DEMOCRITOS Natl Simulat Ctr, I-34014 Trieste, Italy
[3] Univ Barcelona, Fac Fis, Dept Estructura & Constituents Mat, E-08028 Barcelona, Spain
[4] Univ Barcelona, IN2UB, E-08028 Barcelona, Spain
[5] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Fis, Consejo Nacl Invest Cient & Tecn, RA-1428 Buenos Aires, DF, Argentina
来源
PHYSICAL REVIEW B | 2009年 / 79卷 / 10期
关键词
bubbles; caesium; density functional theory; drops; helium; indentation; nanostructured materials; nucleation; wetting; 1ST-ORDER WETTING TRANSITIONS; THIN LIQUID-FILMS; CONTACT-ANGLE; PHASE-TRANSITIONS; CONFINED SYSTEMS; CESIUM METAL; LINE TENSION; HE-4; ADSORPTION; NUCLEATION;
D O I
10.1103/PhysRevB.79.104514
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We investigate the effects (on the wetting characteristics of helium below 3 K) of tailoring an alkali-metal surface by incorporating a regular array of nanoscopic indentations. We establish the prewetting line of helium on semi-infinite planar Cs up to 3 K in the frame of a finite-range temperature-dependent density-functional theory, and examine the modifications introduced in the isotherms when the substrate is covered with a periodic lattice of parabolic cavities. We show that, both for the planar and nanostructured surfaces, the unstable regions of the isotherms are stabilized by nucleation of drops and/or bubbles. Results corresponding to nonwettable Cs surfaces are compared with those obtained both for planar and nanopatterned Na substrates, where wetting at zero temperature is instead expected to occur, for a planar surface, preceded by a first-order prewetting transition.
引用
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页数:11
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