Distribution of Light Elements in Multicrystalline Silicon for Solar Cells Grown by Directional Solidification

被引:7
作者
Matsuo, Hitoshi [1 ]
Hisamatsu, Sho [1 ]
Kangawa, Yoshihiro [1 ,2 ]
Kakimoto, Koichi [1 ,2 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Fukuoka 8168580, Japan
[2] Kyushu Univ, Res Inst Appl Mech, Fukuoka 8168580, Japan
关键词
directional solidification; elemental semiconductors; ingots; precipitation; silicon; silicon compounds; solar cells; OXYGEN PRECIPITATION; GRAIN-BOUNDARY; POLYCRYSTALLINE; SEGREGATION; NITROGEN; CARBON;
D O I
10.1149/1.3155433
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We investigated the relationship between the formation of small grains and the distribution of precipitates such as Si3N4 and SiON in a multicrystalline silicon ingot grown by the unidirectional solidification method. Si3N4 precipitates were mainly observed inside the small grain region, while SiON was mainly precipitated outside the small grain region. SiON started to precipitate before the formation of Si3N4 precipitates. Therefore, precipitation of SiON before precipitation of Si3N4 is a candidate in the formation of small grains.
引用
收藏
页码:H711 / H715
页数:5
相关论文
共 23 条
[1]   Study on defects and impurities in cast-grown polycrystalline silicon substrates for solar cells [J].
Arafune, K ;
Sasakia, T ;
Wakabayashi, F ;
Terada, Y ;
Ohshita, Y ;
Yamaguchi, M .
PHYSICA B-CONDENSED MATTER, 2006, 376 :236-239
[2]  
Arafune K., 2007, P FOR SCI TECHN SIL, P346
[3]   Directional solidification of polycrystalline silicon ingots by successive relaxation of supercooling method [J].
Arafune, Koji ;
Ohishi, Eichiro ;
Sai, Hitoshi ;
Ohshita, Yoshio ;
Yamaguchi, Masafumi .
JOURNAL OF CRYSTAL GROWTH, 2007, 308 (01) :5-9
[4]   THE EFFECTS OF GAS-PHASE CONVECTION ON CARBON CONTAMINATION OF CZOCHRALSKI-GROWN SILICON [J].
BORNSIDE, DE ;
BROWN, RA ;
FUJIWARA, T ;
FUJIWARA, H ;
KUBO, T .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (08) :2790-2804
[5]   Directional solidification of multicrystalline silicon using the accelerated crucible rotation technique [J].
Ganesh, R. Bairava ;
Matsuo, Hitoshi ;
Kangawa, Yoshihiro ;
Arafune, Koji ;
Ohshita, Yoshio ;
Yamaguchi, Masafumi ;
Kakimoto, Koichi .
CRYSTAL GROWTH & DESIGN, 2008, 8 (07) :2525-2527
[6]   Oxygen transportation during Czochralski silicon crystal growth [J].
Hoshikawa, K ;
Huang, XM .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2000, 72 (2-3) :73-79
[7]   DETERMINATION OF CONVERSION FACTOR FOR INFRARED MEASUREMENT OF OXYGEN IN SILICON [J].
IIZUKA, T ;
TAKASU, S ;
TAJIMA, M ;
ARAI, T ;
NOZAKI, T ;
INOUE, N ;
WATANABE, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (07) :1707-1713
[8]   Effect of grain size and dislocation density on the performance of thin film polycrystalline silicon solar cells [J].
Imaizumi, M ;
Ito, T ;
Yamaguchi, M ;
Kaneko, K .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (11) :7635-7640
[9]   Segregation of oxygen at a solid/liquid interface in silicon [J].
Kakimoto, K ;
Ozoe, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (05) :1692-1695
[10]  
LAUX H, 2006, P 21 EUR PHOT SPEC C, P4