MnO Nanoparticles Interdispersed in 3D Porous Carbon Framework for High Performance Lithium-Ion Batteries

被引:73
|
作者
Wang, Shengbin [1 ]
Xing, Yalan [1 ]
Xu, Huaizhe [2 ]
Zhang, Shichao [1 ]
机构
[1] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China
[2] Beihang Univ, Ctr Mat Phys & Chem, Beijing 100191, Peoples R China
基金
中国国家自然科学基金;
关键词
MnO; interconnected carbon network; carbon framework; porous structure; lithium-ion batteries; CAPACITY ANODE MATERIAL; ELECTRODE PERFORMANCE; DOPED GRAPHENE; NANOTUBES; OXIDE; NANOCOMPOSITES; NANOCRYSTALS; HYBRID;
D O I
10.1021/am5027055
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Interdispersed MnO nanoparticles that are anchored and encapsulated in a three-dimensional (3D) porous carbon framework (MnO@CF) have been constructed, which display nanosphere architecture with rich porosity, well-defined carbon framework configuration, and excellent structure stability. When evaluated as an anode material, the MnO@CF exhibits relatively high specific capacity of 939 mA h g(-1) at current rate of 0.2 A g(-1) over 200 cycles and excellent rate capability of 560.2 mA h g 4 A g(-1). By virtue of its mechanical stability and desirable ionic/electronic conductivity, the specific design can be a promising approach to fabricate high-performance lithium-ion batteries.
引用
收藏
页码:12713 / 12718
页数:6
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