Thermal vacancies in one-dimensional Xe adsorbate chains in grooves of nanotube bundles

被引:15
作者
Bagatskii, M. I. [1 ]
Barabashko, M. S. [1 ]
Sumarokov, V. V. [1 ]
机构
[1] Natl Acad Sci Ukraine, Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine
关键词
SINGLE-WALLED CARBON; HEAT-CAPACITY; EXPANSION; XENON; GASES;
D O I
10.1134/S0021364014080049
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The specific heat C (P) of quasi-one-dimensional Xe adsorbate chains in grooves on the outer surface of closed single-walled carbon nanotube bundles in the temperature interval of 2-55 K has been measured. Experimental data have been compared to the theoretical C (V) values. The sharp increase in the difference C (P) - C (V) above 30 K has been explained within the model of formation of single thermal vacancies in the one-dimensional Xe adsorbate chains. The enthalpy, entropy, and concentration of thermal vacancies have been determined.
引用
收藏
页码:461 / 465
页数:5
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