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A rhodamine-based fluorescent sensor for the highly selective and sensitive detection of mercury in aqueous solution and living cells
被引:15
|作者:
Liu, Daying
[1
]
Qi, Jing
[1
]
Liu, Xiaoyan
[1
]
Cui, Zhigang
[2
]
Chang, Hexi
[2
]
Chen, Jiatong
[3
]
He, Huarui
[2
]
Yang, Guangming
[1
]
机构:
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Heowns Biochem Technol LLC, Tianjin, Peoples R China
[3] Nankai Univ, Dept Biochem & Mol Biol, Tianjin 300071, Peoples R China
基金:
中国国家自然科学基金;
关键词:
ION;
CADMIUM;
MEDIA;
CD2+;
D O I:
10.1039/c4ay00641k
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
A novel Hg2+-selective fluorescent sensor (Sensor-Hg) based on a rhodamine scaffold, with N-Ethylthioethyl-N-[N',N'-(2'-Diethylthioethylamino)-5'-methyl-Phenoxyethyl]-2-Methoxy Aniline (EDPMA) as a receptor, has been developed. Sensor-Hg exhibited similar to 35-fold enhancement in fluorescence emission upon binding with Hg2+, with a characteristic emission band of rhodamine at similar to 585 nm. It demonstrates high selectivity and sensitivity for detecting Hg2+ in aqueous solution and living cells.
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页码:3578 / 3581
页数:4
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