A rhodamine-based fluorescent sensor for the highly selective and sensitive detection of mercury in aqueous solution and living cells

被引:15
|
作者
Liu, Daying [1 ]
Qi, Jing [1 ]
Liu, Xiaoyan [1 ]
Cui, Zhigang [2 ]
Chang, Hexi [2 ]
Chen, Jiatong [3 ]
He, Huarui [2 ]
Yang, Guangming [1 ]
机构
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Heowns Biochem Technol LLC, Tianjin, Peoples R China
[3] Nankai Univ, Dept Biochem & Mol Biol, Tianjin 300071, Peoples R China
基金
中国国家自然科学基金;
关键词
ION; CADMIUM; MEDIA; CD2+;
D O I
10.1039/c4ay00641k
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A novel Hg2+-selective fluorescent sensor (Sensor-Hg) based on a rhodamine scaffold, with N-Ethylthioethyl-N-[N',N'-(2'-Diethylthioethylamino)-5'-methyl-Phenoxyethyl]-2-Methoxy Aniline (EDPMA) as a receptor, has been developed. Sensor-Hg exhibited similar to 35-fold enhancement in fluorescence emission upon binding with Hg2+, with a characteristic emission band of rhodamine at similar to 585 nm. It demonstrates high selectivity and sensitivity for detecting Hg2+ in aqueous solution and living cells.
引用
收藏
页码:3578 / 3581
页数:4
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