The functionalization of saturated hydrocarbons .39. Further evidence for the role of the iron-carbon bond in Gif chemistry

被引：14
作者：
Barton, DHR
Salgueiro, MC
MacKinnon, J
机构：
[1] Department of Chemistry, Texas A and M University, College Station
[2] Departamento de Quimica, Universitat de Girona, 17071, Girona, Placa Hospital
来源：
TETRAHEDRON | 1997年 / 53卷 / 22期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1016/S0040-4020(97)00447-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The functionalization of saturated hydrocarbons utilizing the Gif oxidation system is considered to occur via an intermediate containing an Fe-C bond. Iodine and iodide ion have been found to capture efficiently the Fe-C bond to give the corresponding alkyl iodide in both the Fe-II-Fe-IV and Fd(III)-Fe-V manifolds. This trapping of the Fe-C bond in both manifolds is shown to be non-radical in nature. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码：7417 / 7428
页数：12
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