Ion Effects on Liquid Structure of Water Monitored by Terahertz Time-Domain Spectroscopy

被引:0
作者
Kondoh, Masato [1 ]
Ohshima, Yasuhiro [2 ]
Tsubouchi, Masaaki [1 ,2 ]
机构
[1] Japan Atom Energy Agcy, Kansai Photon Sci Inst, Quantum Beam Sci Directorate, 8-1 Umemidai, Kizu, Kyoto 6190215, Japan
[2] Natl Inst Nat Sci, Inst Mol Sci, Okazaki, Aichi 4448585, Japan
来源
2013 38TH INTERNATIONAL CONFERENCE ON INFRARED, MILLIMETER, AND TERAHERTZ WAVES (IRMMW-THZ) | 2013年
关键词
AQUEOUS-SOLUTIONS;
D O I
暂无
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
We have investigated dielectric relaxation in aqueous ionic solutions by terahertz time-domain spectroscopy to elucidate the ionic hydration effect on the structure of water. Our finding suggests the dissolved ion induces the "structure breaking effect" which weakens the hydrogen bonding of water beyond the ion hydration shell.
引用
收藏
页数:2
相关论文
共 8 条
  • [1] Dielectric spectroscopy of aqueous solutions of KCl and CsCl
    Chen, T
    Hefter, G
    Buchner, R
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (20) : 4025 - 4031
  • [2] STRUCTURAL ASPECTS OF ION-SOLVENT INTERACTION IN AQUEOUS SOLUTIONS - A SUGGESTED PICTURE OF WATER STRUCTURE
    FRANK, HS
    WEN, WY
    [J]. DISCUSSIONS OF THE FARADAY SOCIETY, 1957, (24): : 133 - 140
  • [3] Perturbation of water structure due to monovalent ions in solution
    Mancinelli, R.
    Botti, A.
    Bruni, F.
    Ricci, M. A.
    Soper, A. K.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (23) : 2959 - 2967
  • [4] Effect of Ions on the Structure of Water: Structure Making and Breaking
    Marcus, Yizhak
    [J]. CHEMICAL REVIEWS, 2009, 109 (03) : 1346 - 1370
  • [5] Negligible effect of ions on the hydrogen-bond structure in liquid water
    Omta, AW
    Kropman, MF
    Woutersen, S
    Bakker, HJ
    [J]. SCIENCE, 2003, 301 (5631) : 347 - 349
  • [6] Rattling in the Cage: Ions as Probes of Sub-picosecond Water Network Dynamics
    Schmidt, Diedrich A.
    Birer, Oezguer
    Funkner, Stefan
    Born, Benjamin P.
    Gnanasekaran, Ramachandran
    Schwaab, Gerhard W.
    Leitner, David M.
    Havenith, Martina
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (51) : 18512 - 18517
  • [7] Anisotropic Water Reorientation around Ions
    Tielrooij, K. J.
    van der Post, S. T.
    Hunger, J.
    Bonn, M.
    Bakker, H. J.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2011, 115 (43) : 12638 - 12647
  • [8] Origin of the fast relaxation component of water and heavy water revealed by terahertz time-domain attenuated total reflection spectroscopy
    Yada, Hiroyuki
    Nagai, Masaya
    Tanaka, Koichiro
    [J]. CHEMICAL PHYSICS LETTERS, 2008, 464 (4-6) : 166 - 170