Thiol-capping of CdTe nanocrystals:: An alternative to organometallic synthetic routes

被引:1474
作者
Gaponik, N [1 ]
Talapin, DV [1 ]
Rogach, AL [1 ]
Hoppe, K [1 ]
Shevchenko, EV [1 ]
Kornowski, A [1 ]
Eychmüller, A [1 ]
Weller, H [1 ]
机构
[1] Univ Hamburg, Inst Phys Chem, D-20146 Hamburg, Germany
关键词
D O I
10.1021/jp025541k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
New approaches to synthesize photostable thiol-capped CdTe nanocrystals are reported. Post-preparative size-selective precipitation and selective photochemical etching have been developed as methods providing an increase of photoluminescence quantum efficiency of the nanocrystals of up to 40%. Some advantages of thiol-capping in comparison to conventional organometallic syntheses of quantum dots are discussed.
引用
收藏
页码:7177 / 7185
页数:9
相关论文
共 66 条
[1]   Photochemical instability of CdSe nanocrystals coated by hydrophilic thiols [J].
Aldana, J ;
Wang, YA ;
Peng, XG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (36) :8844-8850
[2]   Quantum-dot concentrator and thermodynamic model for the global redshift [J].
Barnham, K ;
Marques, JL ;
Hassard, J ;
O'Brien, P .
APPLIED PHYSICS LETTERS, 2000, 76 (09) :1197-1199
[3]   Semiconductor nanocrystals as fluorescent biological labels [J].
Bruchez, M ;
Moronne, M ;
Gin, P ;
Weiss, S ;
Alivisatos, AP .
SCIENCE, 1998, 281 (5385) :2013-2016
[4]  
BRUCHEZ M, COMMUNICATION
[5]   Growth and properties of semiconductor core/shell nanocrystals with InAs cores [J].
Cao, YW ;
Banin, U .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) :9692-9702
[6]   Quantum dot bioconjugates for ultrasensitive nonisotopic detection [J].
Chan, WCW ;
Nie, SM .
SCIENCE, 1998, 281 (5385) :2016-2018
[7]   HIGHLY MONODISPERSE QUANTUM SIZED CDS PARTICLES BY SIZE-SELECTIVE PRECIPITATION [J].
CHEMSEDDINE, A ;
WELLER, H .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1993, 97 (04) :636-637
[8]  
COLVIN VL, 1994, NATURE, V370, P354, DOI 10.1038/370354a0
[9]   (CdSe)ZnS core-shell quantum dots: Synthesis and characterization of a size series of highly luminescent nanocrystallites [J].
Dabbousi, BO ;
RodriguezViejo, J ;
Mikulec, FV ;
Heine, JR ;
Mattoussi, H ;
Ober, R ;
Jensen, KF ;
Bawendi, MG .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (46) :9463-9475
[10]  
DEMAS JN, 1971, J PHYS CHEM-US, V75, P991, DOI 10.1021/j100678a001