Loss of implanted heavy elements during annealing of ultra-shallow ion-implanted silicon: The complete picture

被引:4
作者
Chan, T. K. [1 ]
Koh, S. Y. [1 ]
Fang, V. [2 ]
Markwitz, A. [2 ,3 ]
Osipowicz, T. [1 ]
机构
[1] Natl Univ Singapore, Dept Phys, Ctr Ion Beam Applicat, Singapore 117551, Singapore
[2] GNS Sci, Dept Ion Beam Technol, Gracefield 5010, New Zealand
[3] MacDiarmid Inst Adv Mat & Nanotechnol, Wellington, New Zealand
关键词
Ion implantation; Ultra-shallow junctions; Dopant dose loss; Group IV alloys; High-resolution RBS; Crystal regrowth; AMORPHOUS-SILICON; DIFFUSION; PB; SI; CRYSTAL; CARBON; INDIUM; PHASE; RBS;
D O I
10.1016/j.apsusc.2014.06.030
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
From the observations of the annealing process of ultra-shallow Sn and Pb implanted Si, we propose the mechanism and the triggering conditions for the dopant dose loss effect commonly observed in heavy ion-implanted silicon. The results of high-resolution Rutherford backscattering spectrometry, high-resolution cross-sectional transmission electron microscopy and Monte Carlo simulations are presented. With these results, we construct a complete chain of events that leads to the loss of most of the implanted ions. First, the implanted atoms agglomerate into liquid melts during high temperature electron beam annealing, causing polycrystalline phase formation. Next, liquid phase movement takes place along grain boundaries, and the implanted atoms are forced out of the surface layer as the grain boundaries disappear during grain growth, leaving behind low concentrations of residual atoms. The specific conditions that trigger such a sequence of processes are identified. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:322 / 330
页数:9
相关论文
共 26 条
[1]  
[Anonymous], SI SN BIN PHAS DIAGR
[2]  
[Anonymous], SI PB BIN PHAS DIAGR
[3]   Annealing of ion implanted CdZnO [J].
Azarov, A. Yu ;
Hallen, A. ;
Svensson, B. G. ;
Kuznetsov, A. Yu .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2012, 45 (23)
[4]   T-DYN MONTE-CARLO SIMULATIONS APPLIED TO ION ASSISTED THIN-FILM PROCESSES [J].
BIERSACK, JP ;
BERG, S ;
NENDER, C .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1991, 59 :21-27
[5]   Solid phase epitaxy of ultra-shallow Sn implanted Si observed using high-resolution Rutherford backscattering spectrometry [J].
Chan, T. K. ;
Fang, F. ;
Markwitz, A. ;
Osipowicz, T. .
APPLIED PHYSICS LETTERS, 2012, 101 (08)
[6]   Implant damage and redistribution of indium in indium-implanted thin silicon-on-insulator [J].
Chen, P ;
An, ZH ;
Zhu, M ;
Fu, RKY ;
Chu, PK ;
Montgomery, N ;
Biswas, S .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2004, 114 :251-254
[7]   Diffusion behavior of cesium in silicon carbide at T > 1000 °C [J].
Friedland, E. ;
van der Berg, N. G. ;
Hlatshwayo, T. T. ;
Kuhudzai, R. J. ;
Malherbe, J. B. ;
Wendler, E. ;
Wesch, W. .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2012, 286 :102-107
[8]   Diffusion of indium implanted in silicon: The effect of the pre-amorphisation treatment and of the presence of carbon [J].
Gennaro, S ;
Barozzi, M ;
Bersani, M ;
Sealy, BJ ;
Gwilliam, R .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2005, 237 (1-2) :88-92
[9]   Pulsed laser annealing of Sn-implanted Si single crystal [J].
Klinger, D ;
Auleytner, J ;
Zymierska, D ;
Kozankiewicz, B ;
Nowicki, L ;
Stonert, A .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2331-2336
[10]   New classes of Si-based photonic materials and device architectures via designer molecular routes [J].
Kouvetakis, John ;
Chizmeshya, Andrew V. G. .
JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (17) :1649-1655