Access to the structures of fluoromagnesium compounds:: synthesis and structural characterization of the β-diketiminato magnesium fluoride [{CH(CMeNAr)2}Mg(μ-F)(THF)]2•toluene

被引：39

作者：

Hao, HJ ^{[1
]}

Roesky, HW ^{[1
]}

Ding, YQ ^{[1
]}

Cui, CM ^{[1
]}

Schormann, M ^{[1
]}

Schmidt, HG ^{[1
]}

Noltemeyer, M ^{[1
]}

Zemva, B ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2002年 / 115卷 / 02期

关键词：

magnesium; fluorides; beta-diketiminato ligands; bischelating figands;

D O I：

10.1016/S0022-1139(02)00043-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

beta-Diketiminato magnesium fluoride [{CH(CMeNAr)(2)}Mg(mu-F)(THF)](2)(.)toluene (Ar = 2,6-i-Pr2C6H3, 2(.)toluene) was synthesized. The molecular structure of 2 revealed for the first time, the double fluoro bridge feature between the two magnesium atoms with a typical Mg-F bond length (average 1.95 Angstrom). (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：143 / 147

页数：5

共 19 条

[1] PREPARATION OF ALKYLMAGNESIUM FLUORIDES [J].

ASHBY, EC ;

YU, SH ;

BEACH, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (02) :433-&

[2] COMPOSITION OF GRIGNARD COMPOUNDS .8. ALKYLMAGNESIUM FLUORIDES [J].

ASHBY, EC ;

YU, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 29 (03) :339-&

[3] Synthesis and characterisation of magnesium methyl complexes with monoanionic chelating nitrogen donor ligands and their reaction with dioxygen [J].

Bailey, PJ ;

Dick, CME ;

Fabre, S ;

Parsons, S .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (10) :1655-1661

[4]

Caramanian A, 1999, Z ANORG ALLG CHEM, V625, P933, DOI 10.1002/(SICI)1521-3749(199906)625:6<933::AID-ZAAC933>3.0.CO

[5]

2-N

[6] Chains, planes, and tunnels of metal diphosphonates:: synthesis, structure, and characterization of Na3Co(O3PCH2PO3)(OH), Na3Mg(O3PCH2PO3)F•H2O, Na2Co(O3PCH2PO3)•H2O, NaCo2(O3PCH2CH2CH2PO3)(OH), and CO2(O3PCH2PO3)(H2O) [J].

Distler, A ;

Lohse, DL ;

Sevov, SC .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1805-1812

[7] Novel mono-alkyl magnesium complexes stabilized by a bulky β-diketiminate ligand:: Structural characterization of a coordinatively unsaturated trigonal system [J].

Gibson, VC ;

Segal, JA ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (29) :7120-7121

[8] Syntheses and structures of the first examples of zinc compounds with bridging fluorine and hydrogen atoms [J].

Hao, HJ ;

Cui, CM ;

Roesky, HW ;

Bai, GC ;

Schmidt, HG ;

Noltemeyer, M .

CHEMICAL COMMUNICATIONS, 2001, (12) :1118-1119

[9]

Hao HJ, 2000, Z ANORG ALLG CHEM, V626, P368

[10] CRYSTAL HANDLING AT LOW-TEMPERATURES [J].

KOTTKE, T ;

STALKE, D .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 :615-619

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