Recommended vapor-liquid equilibrium data.: Part 1:: Binary n-alkanol-n-alkane systems

被引：40

作者：

Góral, M ^{[1
]}

Oracz, P

Skrzecz, A

Bok, A

Maczynski, A

机构：

[1] Univ Warsaw, Dept Chem, Warsaw, Poland

[2] Polish Acad Sci, Inst Phys Chem, Warsaw, Poland

来源：

JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA | 2002年 / 31卷 / 03期

关键词：

alcohols; binary systems; hydrocarbons; predicted data; recommended data; vapor-liquid equilibria;

D O I：

10.1063/1.1480097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The recommended vapor-liquid equilibrium (VLE) data for 39 binary n-alcohol-n-alkane systems have been obtained after critical evaluation of all data (490 data sets) reported in the open literature up to the middle of 2001. The evaluation procedure consisted in combining the thermodynamic consistency tests, data correlation, comparison with enthalpy of mixing data, and comparison of VLE data for various mixtures. The data were correlated with equations based on the local compositions concept as well as with the equation of state appended with a chemical term (EoSC) proposed by Goral. The recommended data are presented in the form of individual pages containing tables of data, figures, and auxiliary information. Each page corresponds to one system and contains three isotherms (spaced by at least 15 K) and one isobar (preferably at 101.32 kPa). Experimental gaps were completed with the predicted data. (C) 2002 American Institute of Physics.

引用

页码：701 / 748

页数：48

共 174 条

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[2]

Aristovich V. Y., 1965, ZH PRIKL KHIM, V38, P2694

[3] VAPOR-LIQUID-EQUILIBRIA FOR THE TERNARY-SYSTEM NORMAL-HEPTANE-NORMAL-PROPANOL-1, CHLOROBUTANE AND ITS CONSTITUENT BINARIES AT 318.15-K AND 338.15-K [J].