Mo(W,V)-Cu(Ag)-S(Se) cluster compounds

被引：212
作者：
Hou, HW
Xin, XQ
Shi, S
机构：
[1] NANJING UNIV, DEPT CHEM, STATE KEY LAB COORDINAT CHEM, NANJING 210093, PEOPLES R CHINA
[2] NATL UNIV SINGAPORE, DEPT CHEM ENGN, OPT CRYSTAL LAB, SINGAPORE 117548, SINGAPORE
来源：
COORDINATION CHEMISTRY REVIEWS | 1996年 / 153卷
关键词：
Mo(W; V)-Cu(Ag)-S(Se) cluster compounds; preparation; skeletal structure; reactions; spectroscopic properties; non-linear optical properties;
D O I：
10.1016/0010-8545(95)01224-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This review summarizes the preparation, skeletal structure, reactions, spectroscopic properties and nan-linear optical properties of Mo(W,V)-Cu(Ag)-S(Se) cluster compounds; 190 such compounds belong to 23 structural types; 25 reactions are classified into ligand substitution, addition and decomposition reactions. Recently, some Mo(W)-Cu(Ag)-S clusters were found to exhibit strong non-linear optical properties; the optical limiting threshold measured for [(PPh(3))(4)Ag4Mo2S8] is one order of magnitude lower than that of C-60.
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页码：25 / 56
页数：32
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