Preparation and photoluminescence of monolithic silica glass doped with Tb3+ ions using SiO2-PVA nanocomposite

被引:11
作者
Ikeda, Hiroshi [1 ]
Murata, Takahiro [2 ]
Fujino, Shigeru [1 ]
机构
[1] Kyushu Univ, Art Sci & Technol Ctr Cooperat Res, Kasuga, Fukuoka 8168580, Japan
[2] Kumamoto Univ, Fac Educ & Masters Course Educ, Chuo Ku, Kumamoto 8608555, Japan
关键词
Silica glass; Fluorescence; Rare-earth; Terbium; Organic-inorganic composite; TRANSPARENT FLUORESCENCE MATERIAL; POROUS-GLASS; RARE-EARTH; LUMINESCENCE; EU3+; FABRICATION; GREEN; EU2+;
D O I
10.1016/j.optmat.2014.02.011
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The monolithic silica glass doped with Tb3+ ions was fabricated using the SiO2-PVA nanocomposite as the glass precursor. In order to dope Tb3+ ions in the monolithic silica glass, the mesoporous SiO2-PVA nanocomposite was immersed in the Tb3+ ions contained solution and subsequently sintered at 1100 degrees C in air. Consequently the monolithic transparent silica glass was obtained, exhibiting green fluorescence attributed to D-5(4) -> F-7(5) main transitions under UV excitation. The Tb concentration in the sintered glass could be controlled by immersion time of the nanocomposite in the solution. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:1119 / 1122
页数:4
相关论文
共 20 条
[1]  
Blasse G., 1983, REV INORG CHEM, V5, P319
[2]   LUMINESCENCE OF EU3+ IONS DURING THERMAL DENSIFICATION OF SIO2 GEL [J].
CAMPOSTRINI, R ;
CARTURAN, G ;
FERRARI, M ;
MONTAGNA, M ;
PILLA, O .
JOURNAL OF MATERIALS RESEARCH, 1992, 7 (03) :745-753
[3]   Colorless transparent fluorescence material: Sintered porous glass containing rare-earth and transition-metal ions [J].
Chen, DP ;
Miyoshi, H ;
Akai, T ;
Yazawa, T .
APPLIED PHYSICS LETTERS, 2005, 86 (23) :1-3
[4]   Optical and structural properties of Er3+-doped P2O5-SiO2 and Al203-SiO2 planar waveguides [J].
Hattori, K ;
Kitagawa, T ;
Shuto, K ;
Oguma, M ;
Ohmori, Y .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1998, 54 (1-2) :15-17
[5]   Nature and optical behaviour of heavily europium-doped silica glasses obtained by the sol-gel method [J].
Hreniak, D ;
Jasiorski, M ;
Maruszewski, K ;
Kepinski, L ;
Krajczyk, L ;
Misiewicz, J ;
Strek, W .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 298 (2-3) :146-152
[6]   Fabrication of Au nanoparticles doped bulk silica glass by use of SiO2-PVA nanocomposite [J].
Ikeda, Hiroshi ;
Fujino, Shigeru ;
Kajiwara, Toshihisa .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2012, 120 (1402) :238-242
[7]   Fabrication of Micropatterns on Silica Glass by a Room-Temperature Imprinting Method [J].
Ikeda, Hiroshi ;
Fujino, Shigeru ;
Kajiwara, Toshihisa .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2011, 94 (08) :2319-2322
[8]   Preparation of SiO2-PVA nanocomposite and monolithic transparent silica glass by sintering [J].
Ikeda, Hiroshi ;
Fujino, Shigeru ;
Kajiwara, Toshihisa .
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2011, 119 (1385) :65-69
[9]   Sol-Gel Synthesis of Rare-Earth and Phosphorus Codoped Monolithic Silica Glasses from a Cosolvent-Free Phase-Separating System [J].
Kajihara, Koichi ;
Kuwatani, Shungo ;
Kanamura, Kiyoshi .
APPLIED PHYSICS EXPRESS, 2012, 5 (01)
[10]   Colorless transparent fluorescence material at the VUV excitation:: The leached sintered glass with impregnation of Tb3+ ions [J].
Liu, W ;
Chen, DP ;
Miyoshi, H ;
Kadono, K ;
Akai, T .
CHEMISTRY LETTERS, 2005, 34 (08) :1176-1177