Arylzinc complexes as new initiator systems for the production of isobutene copolymers with high isoprene content

被引：32

作者：

Garratt, S ^{[1
]}

Guerrero, A ^{[1
]}

Hughes, DL ^{[1
]}

Bochmann, M ^{[1
]}

机构：

[1] Univ E Anglia, Sch Chem Sci & Pharm, Wolfson Mat & Catalysis Ctr, Norwich NR4 7TJ, Norfolk, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 16期

关键词：

anions; copolymerization; isobutene; Lewis acids; zinc;

D O I：

10.1002/anie.200353787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Better rubber: The initiator system [Zn(C6F5) 2]/tBuCl for isobutene/isoprene copolymerizations (see scheme) gave products with high molecular weights, significantly increased isoprene incorporation, and minimal cross-linking.

引用

页码：2166 / 2169

页数：4

共 62 条

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