Nonhydrolytic Synthesis of Silanols by the Hydrogenolysis of Benzyloxysilanes

被引：7
作者：
Igarashi, Masayasu [1 ]
Matsumoto, Tomohiro [1 ]
Sato, Kazuhiko [1 ]
Ando, Wataru [1 ]
Shimada, Shigeru [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
来源：
CHEMISTRY LETTERS | 2014年 / 43卷 / 04期
关键词：
HECK-TYPE REACTION; HYDROLYTIC OXIDATION; SILANEDIOLS; CARBON; ANALOG; ARYL; ORGANOSILANOLS; TRANSFORMATION; CATALYSIS; HALIDES;
D O I：
10.1246/cl.131079
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogenolysis of benzyloxysilanes was smoothly catalyzed by Pd/C in THF to give corresponding silanols under nonhydrolytic conditions. The reaction proved to be applicable to various benzyloxysilanes giving silanemonools, diol, and triol.
引用
收藏
页码：429 / 431
页数：3
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