A Novel Method for the Chlorolactonization of Alkenoic Acids Using Diphenyl Sulfoxide/Oxalyl Chloride

被引：19

作者：

Ding, Rui ^{[1
]}

Lan, Liyuan ^{[1
]}

Li, Shuhui ^{[1
]}

Liu, Yongguo ^{[1
]}

Yang, Shaoxiang ^{[1
]}

Tian, Hongyu ^{[1
]}

Sun, Baoguo ^{[1
]}

机构：

[1] Beijing Technol & Business Univ, Beijing Key Lab Flavor Chem, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2018年 / 50卷 / 13期

关键词：

chlorolactonization; alkenoic acids; diphenyl sulfoxide; oxalyl chloride; chlorodiphenylsulfonium salt; UNSATURATED-ACIDS; HYDROGEN-PEROXIDE; SODIUM-BROMIDE; ASYMMETRIC CHLOROLACTONIZATION; CARBOXYLIC-ACIDS; BROMOLACTONIZATION; IODOLACTONIZATION; HALOLACTONIZATION; BROMINATION; ACTIVATION;

D O I：

10.1055/s-0037-1609687

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile chlorolactonization of alkenoic acids by treatment with diphenyl sulfoxide/oxalyl chloride has been developed. The reaction can generate various chlorolactones in moderate to good yields, wherein the chlorodiphenylsufonium salt derived from diphenyl sulfoxide/oxalyl chloride serves as the source of Cl+.

引用

页码：2555 / 2566

页数：12

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