Metal-insulator transition in iodinated amorphous conducting carbon films

被引:16
作者
Kumari, L [1 ]
Subramanyam, S
Eto, S
Takai, K
Enoki, T
机构
[1] Indian Inst Sci, Dept Phys, Bangalore 560012, Karnataka, India
[2] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan
基金
日本学术振兴会;
关键词
carbon films; intercalation; pyrolysis; transport properties;
D O I
10.1016/j.carbon.2004.04.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, the effect of iodine incorporation on the electrical conductivity, magnetic susceptibility (chi) and magnetoresistance (MR) of amorphous conducting carbon (a-C) films has been discussed. Variation in conductivity of a-C films depends on the sample preparation conditions and iodine concentration. Evidence of metal-insulator (M-I) transition as a function of pyrolysis temperature is observed for iodinated (a-C:I) samples. The temperature dependent magnetic susceptibility of a-C:I sample shows a Curie behavior at low temperatures. The positive magnetoresistance is observed for all the samples irrespective of the conduction regimes. This is accounted by the electron-electron interaction in the a-C:I system. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2133 / 2137
页数:5
相关论文
共 12 条
[1]   Electrical measurements of iodine doped amorphous diamondlike films grown on silicon substrate [J].
AllonAlaluf, M ;
Croitoru, N .
APPLIED PHYSICS LETTERS, 1996, 69 (19) :2932-2934
[2]  
[Anonymous], 1995, The Electrical Properties of Disordered Metals
[3]   Electrical resistance and magnetoresistance of pyrocarbon at low temperatures in fields up to 14 Tesla [J].
Faisst, A ;
von Löhneysen, H .
CARBON, 2002, 40 (03) :321-327
[4]   Reversible intercalation of charged iodine chains into carbon nanotube ropes [J].
Grigorian, L ;
Williams, KA ;
Fang, S ;
Sumanasekera, GU ;
Loper, AL ;
Dickey, EC ;
Pennycook, SJ ;
Eklund, PC .
PHYSICAL REVIEW LETTERS, 1998, 80 (25) :5560-5563
[5]   Effect of iodine incorporation on the electrical properties of amorphous conducting carbon films [J].
Kumari, L ;
Prasad, V ;
Subramanyam, SV .
CARBON, 2003, 41 (09) :1841-1846
[6]  
LEE PA, 1985, REV MOD PHYS, V57, P2
[7]  
LEWIS IC, 1981, CHEM PHYS CARBON, V17, P1
[8]  
Mott N. F., 1979, ELECT PROCESSES NONC
[9]  
Reghu M., 1996, HDB CONDUCTING POLYM, P27
[10]   Novel electronic properties of a nano-graphite disordered network and their iodine doping effects [J].
Shibayama, Y ;
Sato, H ;
Enoki, T ;
Bi, XX ;
Dresselhaus, MS ;
Endo, M .
JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2000, 69 (03) :754-767