Kinetic and thermodynamic studies of adsorption of Cu2+ and Pb2+ onto amidoximated bacterial cellulose

被引:48
作者
Chen, Shiyan [1 ]
Shen, Wei [1 ]
Yu, Feng [1 ]
Wang, Huaping [1 ]
机构
[1] Donghua Univ, State Key Lab Modificat Chem Fibers & Polymer Mat, Coll Mat Sci & Engn, Shanghai 201620, Peoples R China
关键词
Adsorption; Kinetics; Thermodynamics; Amidoximated bacterial cellulose; AQUEOUS-SOLUTION; FLUORIDE REMOVAL; COPPER(II) IONS; HEAVY-METALS; BASIC DYE; SORPTION; EQUILIBRIUM; ADSORBENTS; WATER; PARAMETERS;
D O I
10.1007/s00289-009-0088-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Removal of Cu2+ and Pb2+ from aqueous solutions by adsorption onto amidoximated bacterial cellulose (Am-BC) was investigated. The effects of pH, initial concentration, contact time and temperature were studied in batch experiments. The pseudo-first and pseudo-second orders and intraparticle diffusion equation were used to evaluate the kinetic data and the constants were determined. The experimental data fits well to the pseudo-second order kinetic model, which indicates that the chemical adsorption is the rate-determining step, instead of mass transfer. The equilibrium adsorption data were described by the Langmuir, Freundlich, and Temkin isotherms. The Am-BC showed a better fit to the Langmuir isotherm. The separation factor (R (L) ) revealed the favorable nature of the isotherm. The thermodynamic parameters (Delta H (ads) (0) , Delta S (ads) (0) , Delta G (ads) (0) ) for Cu2+ and Pb2+ adsorption onto Am-BC were also determined from the temperature dependence. The values of enthalpy and entropy indicated that this process was spontaneous and exothermic. The experimental studies indicate that Am-BC would be a potential effective adsorbent to remove the metal ions from wastewater.
引用
收藏
页码:283 / 297
页数:15
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