SnO2 Nanoflake Arrays Coated with Polypyrrole on a Carbon Cloth as Flexible Anodes for Sodium-Ion Batteries

被引:95
作者
Wang, Minya [1 ,2 ]
Wang, Xiuli [1 ,2 ]
Yao, Zhujun [1 ,2 ]
Tang, Wangjia [1 ,2 ]
Xia, Xinhui [1 ,2 ]
Gu, Changdong [1 ,2 ]
Tu, Jiangping [1 ,2 ]
机构
[1] Zhejiang Univ, State Key Lab Silicon Mat, Key Lab Adv Mat & Applicat Batteries Zhejiang Pro, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, Sch Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
关键词
lamellar SnO2; conducting polymer; anode; sodium-ion battery; freestanding; HIGH-PERFORMANCE LITHIUM; REDUCED GRAPHENE OXIDE; NA-ION; HIGH-CAPACITY; ASSISTED SYNTHESIS; FACILE SYNTHESIS; STORAGE; COMPOSITE; NANOCOMPOSITES; NANOPARTICLES;
D O I
10.1021/acsami.9b08378
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
SnO2 has been extensively studied as an anode material for sodium-ion batteries, which, however, has long been subjected to poor conductivity and large volume expansion accompanied with an unsatisfactory electrochemical performance. Here, novel interlaced SnO2 nanoflakes are synthesized directly on a carbon cloth collector via hydrothermal and annealing treatment and then coated with polypyrrole (PPy) via electrodeposition. The as -prepared flexible SnO2@PPy on the carbon cloth exhibits a high initial capacity of 1172.1 mAh g(-1) and an outstanding cycling stability with 85% capacity retention after 300 cycles at 0.1 A g(-1), which can be contributed to the interlaced SnO2 nanoflakes as well as the coating of PPy. This result shows promising potential for construction of an electrode in highperformance energy storage fields.
引用
收藏
页码:24198 / 24204
页数:7
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