Highly effective Li2OA/Li3N with ultrafast kinetics for H2 storage

被引:66
作者
Hu, YH [1 ]
Ruckenstein, E [1 ]
机构
[1] SUNY Buffalo, Dept Chem Engn, Buffalo, NY 14260 USA
关键词
D O I
10.1021/ie049947q
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The refueling time and safe hydrogen storage are critical factors in the development of a hydrogen economy for transportation. The finding of a fast and high-capacity H-2 storage material represents a worldwide challenge. The short-term target of the U.S. Department of Energy for a hydrogen storage material is a 4.5 wt % reversible hydrogen capacity. In this paper, we report that reversible 5 wt % H-2 can be reached in only 3 min even at the relatively low temperature of 180 degreesC by a Li2O/Li3N solid material. Furthermore, this material has excellent stability because successive cycles of absorption-desorption did not decrease the reversible hydrogen capacity and absorption rate.
引用
收藏
页码:2464 / 2467
页数:4
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