Insights into the effect of nanoconfinement on molecular interactions

被引：42
作者：
Chen, Yang [1 ]
Wang, Shuangshou [1 ]
Ye, Jin [1 ]
Li, Daojin [1 ]
Liu, Zhen [1 ]
Wu, Xingcai [2 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Analyt Chem Life Sci, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Mesoscop Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
NANOSCALE | 2014年 / 6卷 / 16期
基金：
中国国家自然科学基金;
关键词：
DIOL-CONTAINING BIOMOLECULES; MESOPOROUS SILICA; SELECTIVE ENRICHMENT; PEPTIDOME ANALYSIS; CONFINEMENT; NANOPARTICLES; SURFACE; GLYCOPROTEINS; RECOGNITION; EXTRACTION;
D O I：
10.1039/c4nr01440e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Being confined within nanoscale space, substances may exhibit unique physicochemical properties. The effect of nanoconfinement on molecular interactions is of significance, but a sound understanding has not been established yet. Here we present a quantitative study on boronate affinity (covalent) and electrostatic (non-covalent) interactions confined within mesoporous silica. We show that both interactions were enhanced by the confinement and that the enhancement depended on the closeness of the interacting location, as well as on the difference between the pore size and the molecular size. The overall enhancement could reach 3 orders of magnitude.
引用
收藏
页码：9563 / 9567
页数：5
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