Oxidative transformation of alcohols and organic halides in aqueous solution

被引：10

作者：

Gupta, Neeraj ^{[1
]}

Thakur, Apoorva ^{[1
]}

Bhardwaj, Pushpa ^{[1
]}

机构：

[1] Shoolini Univ, Fac Basic Sci, Dept Chem, Solan 173229, HP, India

来源：

NEW JOURNAL OF CHEMISTRY | 2014年 / 38卷 / 08期

关键词：

QUINOLINIUM CHLOROCHROMATE; CARBONYL-COMPOUNDS; CHROMIUM-REMOVAL; IONIC LIQUID; MECHANISM; KINETICS; WATER; FLUOROCHROMATE; BENZALDEHYDES; MICROWAVE;

D O I：

10.1039/c4nj00393d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient and new methodology for a one pot conversion of organic halides and alcohols to their corresponding aldehydes or ketones has been developed using quinolinium chlorochromate in an aqueous medium without adding any cosolvent. The same protocol has been-applied for the oxidative conversion of 2-(bromomethyl)-5,7-dinitro-1H-indole to its corresponding aldehyde in the presence of sodium hydroxide.

引用

页码：3749 / 3754

页数：6

共 50 条

[1] SODIUM-HYPOCHLORITE AS OXIDANT IN PHASE-TRANSFER CATALYTIC-SYSTEMS .2. OXIDATION OF AROMATIC ALCOHOLS [J].

ABRAMOVICI, S ;

NEUMANN, R ;

SASSON, Y .

JOURNAL OF MOLECULAR CATALYSIS, 1985, 29 (03) :299-303

[2] THE SOMMELET REACTION .3. THE CHOICE OF SOLVENT AND THE EFFECT OF SUBSTITUENTS [J].

ANGYAL, SJ ;

MORRIS, PJ ;

TETAZ, JR ;

WILSON, JG .

JOURNAL OF THE CHEMICAL SOCIETY, 1950, (AUG) :2141-2145

[3] Enantioselective Friedel-Crafts Reactions in Water Using a DNA-Based Catalyst [J].

Boersma, Arnold J. ;

Feringa, Ben L. ;

Roelfes, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (18) :3346-3348

[4] USE OF PYRIDINIUM CHLOROCHROMATE AS METHYLENE OXIDANT IN 5,6-DIHYDROPYRANS - A PRACTICAL, ONE-STEP PREPARATION OF THE ANHYDROMEVALONOLACTONE [J].

BONADIES, F ;

DIFABIO, R ;

BONINI, C .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (09) :1647-1649

[5] Quinolinium fluorochromate: An efficient reagent for the cleavage of C=N of oximes and hydrazones [J].

Bose, DS ;

Narasaiah, AV .

SYNTHETIC COMMUNICATIONS, 2000, 30 (06) :1153-1158

[6]

Cainelli G., 1984, CHROMIUM OXIDATIONS

[7] Removal of chromium from electroplating industry effluents by ion exchange resins [J].

Cavaco, Sofia A. ;

Fernandes, Sandra ;

Quina, Margarida M. ;

Ferreira, Licinio M. .

JOURNAL OF HAZARDOUS MATERIALS, 2007, 144 (03) :634-638

[8] QUINOLINIUM FLUOROCHROMATE (QFC), C9H7NH[CRO3F] - AN IMPROVED CR(VI)-OXIDANT FOR ORGANIC SUBSTRATES [J].

CHAUDHURI, MK ;

CHETTRI, SK ;

LYNDEM, S ;

PAUL, PC ;

SRINIVAS, P .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (07) :1894-1898

[9]

COREY EJ, 1979, TETRAHEDRON LETT, P399

[10] Lewis acids as catalysts in oxidation reactions:: From homogeneous to heterogeneous systems [J].

Corma, A ;

García, H .

CHEMICAL REVIEWS, 2002, 102 (10) :3837-3892

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