X-ray analysis of coals treated with organic liquids. Detailed study of the adduct formed between pyridine molecules and Beulah Zap lignite

被引:6
作者
DuBose, SB [1 ]
Wertz, DL [1 ]
机构
[1] Univ So Mississippi, Dept Chem & Biochem, Hattiesburg, MS 39406 USA
关键词
D O I
10.1021/ef010207t
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Wide-angle X-ray scattering methods indicate that, almost instantly, pyridine molecules penetrate between the nearest layers of the poly-cyclic units of Beulah Zap lignite to form a quasi-stable adduct. The lifetime of this adduct is several hours, and even after most of the pyridine has evaporated from the BZ/PYR gel, the expanded interlayer distance characteristic of the gel is retained.
引用
收藏
页码:669 / 675
页数:7
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