Low-cost analytic method for the identification of Cinnamon adulteration

被引:31
作者
Cantarelli, Miguel A. [1 ]
Moldes, Carlos A. [1 ,2 ]
Marchevsky, Eduardo J. [3 ]
Azcarate, Silvana M. [1 ,2 ]
Camina, Jose M. [1 ,2 ]
机构
[1] Univ Nacl La Pampa, Fac Ciencias Exactas & Nat, Av Uruguay 151, RA-6300 Santa Rosa, La Pampa, Argentina
[2] Univ Nacl La Pampa, Inst Ciencias Tierra & Ambientales La Pampa INCIT, Mendoza 109, RA-6300 Santa Rosa, La Pampa, Argentina
[3] Inst Quim San Luis INQUISAL, RA-5700 San Luis, Argentina
关键词
Cinnamon; Adulteration; Infrared spectroscopy; Chemometric;
D O I
10.1016/j.microc.2020.105513
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this work, a novel low-cost and non-destructive method for true cinnamon authentication -based on Near-infrared diffuse reflectance spectroscopy and chemometrics- is presented. The use of cinnamon as a spice and flavouring agent is widespread throughout the world. Due to its high cost, true cinnamon -Cinnamon verum, which is only produced in Sri Lanka- it is adulterated with Cinnamon cassia due to its low commercial value. On the other hand, Cinnamon cassia contain a high content of coumarin (1%) which is a family of compounds containing 1,2-benzopyrone structures that are present only in minimal amounts in the barks of Cinnamon verum (0.04%). Due hepatotoxic effects of coumarin in animals and sensitive persons, the Food Safety Regulatory Agencies have imposed restrictions on the use of coumarin in their countries. Near-infrared diffuse reflectance spectroscopy (NIRS) and chemometric analysis were used jointly for evaluate adulterations of true cinnamon.
引用
收藏
页数:6
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