Nucleation at liquid | liquid interfaces:: galvanostatic study

被引：50
作者：
Johans, C
Kontturi, K
Schiffrin, DJ
机构：
[1] Helsinki Univ Technol, Phys Chem & Electrochem Lab, FIN-02015 Helsinki, Finland
[2] Univ Liverpool, Dept Chem, Ctr Nanoscale Sci, Liverpool L69 7ZD, Merseyside, England
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2002年 / 526卷 / 1-2期
关键词：
nucleation; electrodeposition; nanoparticles; palladium; ITIES; liquid vertical bar liquid;
D O I：
10.1016/S0022-0728(02)00763-5
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Electrochemical nucleation at a liquid I liquid interface has been studied by cyclic voltammetry and galvanostatic measurements. A model of general applicability to any current/potential transient was developed for three-dimensional nucleation and growth, yielding information on particle number density. The experimental data was analyzed with this model. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：29 / 35
页数：7
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