A Porous Polyhedral Metal-Organic Framework Based on Zn2(COO)3 and Zn2(COO)4 SBUs

被引：59

作者：

Wu, Mingyan ^{[1
]}

Jiang, Feilong ^{[1
]}

Wei, Wei ^{[1
]}

Gao, Qiang ^{[1
]}

Huang, Yougui ^{[1
]}

Chen, Lian ^{[1
]}

Hong, Maochun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 06期

基金：

中国国家自然科学基金;

关键词：

RETICULAR CHEMISTRY; DESIGN; CAGES;

D O I：

10.1021/cg900153m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A porous polyhedral metal-organic framework has been constructed by utilizing Zn-2(COO)(4) and Zn-2(COO)(3) SBUs as nodes and the flexible hexacarboxylate as linkers. The framework contains four types of interconnected polyhedral cages, rhombic dodecahedron, tetrahedron, octahedron, and distorted tetragonal prism. To identify the topology of the whole network, the four types of polyhedral cages can be viewed as nodes, and the whole network is signed as a (6,6,12,12) network. In another view of point, the Zn-2(COO)(3) SBU, Zn-2(COO)(4) SBU and hexacarboxylate ligands can also be considered as nodes, then the network is simply signed as a (3,4,6)-connected net with a Schlafli symbol (4(3)) (4(4)6(2)) (4(6)7(9)).

引用

页码：2559 / 2561

页数：3

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