Crystal structure and luminescence of antimony(III) bromide with aniline

被引：22

作者：

Bukvetskii, B. V. ^{[1
]}

Sedakova, T. V. ^{[1
]}

Mirochnik, A. G. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 50卷 / 02期

基金：

俄罗斯基础研究基金会;

关键词：

crystal structure; antimony(III); aniline; luminescence; PHOTOLUMINESCENCE; COMPLEXES;

D O I：

10.1007/s10947-009-0044-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The atomic structure of antimony(III) bromide crystals with anilinium was determined by X-ray diffraction analysis of (C6H5NH3)(2)SbBr5 (a = 19.704(3) A..., b = 7.914(1) A..., c = 25.556(4) A...; space group Pbca, Z = 8, rho(calc) = 2.365 g/cm(3)). The crystal structure consists of infinite chains of [SbBr5](2-) complex anions formed by sharing six vertices and the anilinium (C6H5NH3)(+) cations, through which the chains are linked in layers by N-H...Br hydrogen bonds. The geometrical aspects that determine the luminescent spectral properties of the complex are discussed.

引用

页码：322 / 327

页数：6

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