Modulating the rate of charge transport in a metal-organic framework thin film using host: guest chemistry

被引：64
作者：
Hod, Idan [1 ]
Farha, Omar K. [1 ,2 ]
Hupp, Joseph T. [1 ]
机构：
[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 08期
关键词：
ASSISTED LIGAND INCORPORATION; ELECTRICAL-CONDUCTIVITY; ENERGY-TRANSFER; LIGHT; GROWTH; FUNCTIONALIZATION; COMPLEXATION; CYCLODEXTRIN; DEPOSITION; REDUCTION;
D O I：
10.1039/c5cc09695b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Herein we demonstrate the use of host-guest chemistry to modulate rates of charge transport inmetal-organic framework (MOF) films. The kinetics of site-to-site of charge hopping and, in turn, the overall redox conductivity, of a ferrocene-modified MOF can be altered by up to 30-fold by coupling electron exchange to the oxidation-state-dependent formation of inclusion complexes between cyclodextrin and channel-tethered metallocenes.
引用
收藏
页码：1705 / 1708
页数：4
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