Modulating the rate of charge transport in a metal-organic framework thin film using host: guest chemistry

被引：64

作者：

Hod, Idan ^{[1
]}

Farha, Omar K. ^{[1
,2
]}

Hupp, Joseph T. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA

[2] King Abdulaziz Univ, Fac Sci, Dept Chem, Jeddah, Saudi Arabia

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 08期

关键词：

ASSISTED LIGAND INCORPORATION; ELECTRICAL-CONDUCTIVITY; ENERGY-TRANSFER; LIGHT; GROWTH; FUNCTIONALIZATION; COMPLEXATION; CYCLODEXTRIN; DEPOSITION; REDUCTION;

D O I：

10.1039/c5cc09695b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we demonstrate the use of host-guest chemistry to modulate rates of charge transport inmetal-organic framework (MOF) films. The kinetics of site-to-site of charge hopping and, in turn, the overall redox conductivity, of a ferrocene-modified MOF can be altered by up to 30-fold by coupling electron exchange to the oxidation-state-dependent formation of inclusion complexes between cyclodextrin and channel-tethered metallocenes.

引用

页码：1705 / 1708

页数：4

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