A Novel Heterometallic Cluster-Based Coordinational Polymer with 2-[Bis-(2-hydroxy-ethyl)-Amino]-Ethanesulfonic Acid: Synthesis and Crystal Structure

被引：12

作者：

Zhang, Chun Lian ^{[1
]}

Jiang, Xi Fu ^{[1
]}

Yang, Li ^{[1
]}

Zhang, Shu Hua ^{[1
]}

Shi, Shao Ming ^{[2
]}

机构：

[1] Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China

[2] Liu Zhou Vocat & Tech Coll, Liuzhou 545006, Guangxi, Peoples R China

来源：

JOURNAL OF CLUSTER SCIENCE | 2014年 / 25卷 / 02期

关键词：

Coordination polymer; Crystal structure; Chiral synthesis; METAL-ORGANIC FRAMEWORK; COPPER(II) COMPLEX; LIGAND; THERMOANALYSIS;

D O I：

10.1007/s10876-013-0624-x

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rare heterometallic cluster-based polymer [Cu-4(Hbhea)(4)(mu (2)-OCH3) K(CH3OH))] (n) center dot(H2O) (n) (1) (H(3)bhea = 2-[bis-(2-hydroxy-ethyl)-amino]-ethanesulfonic acid), has been synthesized and structurally determined by single crystal X-ray diffraction, elemental analysis. Crystallographic unit of 1 consists of four Cu(II), four Hbhea ligands, one methanol molecule, one methanol anion, one K ion and one crystal lattice water and formed anion cluster [Cu-4(Hbhea)(4)(CH3O)](-) which further constructed a 3-D polymer by linking the six-coordination K ions.

引用

页码：459 / 466

页数：8

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