Rh-Catalyzed oxidative C-H activation/annulation: converting anilines to indoles using molecular oxygen as the sole oxidant

被引：120

作者：

Zhang, Guoying ^{[1
]}

Yu, Hui ^{[1
]}

Qin, Guiping ^{[1
]}

Huang, Hanmin ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 33期

基金：

中国国家自然科学基金;

关键词：

EFFICIENT SYNTHESIS; CYCLIZATION; BOND; FUNCTIONALIZATION; ACTIVATION; ACETANILIDES; HAPALINDOLES; ANNULATION; POTASSIUM; AMINATION;

D O I：

10.1039/c3cc49751h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A practical and efficient Rh(III)-catalyzed aerobic C-H activation has been developed for the facile synthesis of a broad range of indoles from simple anilines and alkynes. The protocol could be conducted under mild conditions and used environmentally friendly oxygen as the sole clear oxidant.

引用

页码：4331 / 4334

页数：4

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