Control of chemo- and regio-selectivity in rhodium catalysed reactions of unsaturated amines with H-2/CO

被引：5

作者：

Bergmann, DJ

Campi, EM

Jackson, WR

McCubbin, QJ

Patti, AF

机构：

[1] Department of Chemistry, Monash University, Clayton

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 24期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/S0040-4039(97)00889-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium catalysed reactions of N-allyl- and N-butenyl-1,3-diaminopropanes give single products arising from exclusive hydroformylation at the terminal carbon when the hindered bisphosphite ligand, BIPHEPHOS is used. Reactions using a high carbon monoxide : hydrogen ratio (9:1) and triphenylphosphine as ligand give predominantly lactams arising From carbonylation but with poor control of regioselectivity. (C) 1997 Elsevier Science Ltd.

引用

页码：4315 / 4318

页数：4

共 9 条

[1]

[Anonymous], [No title captured], Patent No. 4668651

[2]

BILLIG E, 1989, Patent No. 4769498

[3]

BRANDANGE S, 1984, ACTA CHEM SCAND, V6, P526

[4] 1,5-DIAZABICYCLO[4.3.0.]NONANE, THE OXIDATION-PRODUCT OF SPERMINE [J].