A novel ligand-unsupported 3D framework polymer of trimeric copper(I)) and its NLO property

被引：67

作者：

Kang, Y ^{[1
]}

Yao, YG ^{[1
]}

Qin, YY ^{[1
]}

Zhang, J ^{[1
]}

Chen, YB ^{[1
]}

Li, ZJ ^{[1
]}

Wen, YH ^{[1
]}

Cheng, JK ^{[1
]}

Hu, RF ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 09期

关键词：

D O I：

10.1039/b401345j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel 3-D coordination polymer with trimeric copper (I) unit, [Cu-3(CN)(IN)(2)](n) (IN = isonicotinate), was hydrothermally synthesized by the reaction of Cu(NO3)(2).3H(2)O with isonicotinic and terephthalic acids. The structure was characterized to be a twofold interpenetrated 3-D coordination network polymer with two-coordinated copper(I). It has a powder SHG efficiency about that of KDP.

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页码：1046 / 1047

页数：2

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