Thermoplastic Elastomers from Vegetable Oils via Reversible Addition-Fragmentation Chain Transfer Polymerization

被引：0

作者：

Hernandez, Nacu ^{[1
]}

Yan, Mengguo ^{[1
]}

Williams, R. Christopher ^{[2
]}

Cochran, Eric ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA

[2] Iowa State Univ, Dept Civil Construct & Environm Engn, Ames, IA 50011 USA

来源：

GREEN POLYMER CHEMISTRY: BIOBASED MATERIALS AND BIOCATALYSIS | 2015年 / 1192卷

关键词：

LIVING RADICAL POLYMERIZATION; SOYBEAN OIL; RAFT PROCESS; FATTY-ACIDS; POLYURETHANES; POLYOLS; POLYMERS; MONOMERS; STYRENE;

D O I：

暂无

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

We present the controlled radical polymerization of vegetable oils, e.g. soybean oil, with styrene into thermoplastic elastomers. We have discovered that under certain reaction conditions controlled radical polymerization, such as RAFT, limits the number of initiation sites and drastically reduces the rate of chain transfers and termination reactions. This discovery introduces the capability of producing customized chain architectures such as block copolymers (BCPs) from vegetable oils. Here we report the synthesis of poly(styrene-b-AESO-b-styrene) (PS-PAESO-PS) triblock copolymers with properties similar to petroleum based thermoplastic elastomers.

引用

页码：183 / 199

页数：17

共 32 条

[1] Novel rubbers from cationic copolymerization of soybean oils and dicyclopentadiene. 1. Synthesis and characterization [J].

Andjelkovic, DD ;

Larock, RC .

BIOMACROMOLECULES, 2006, 7 (03) :927-936

[2] Thermodynamics of Chain Architecture in Acrylic Block Terpolymers [J].

Bergman, James A. ;

Hernandez, Nacu B. ;

Cochran, Eric W. ;

Heinen, Jennifer M. .

MACROMOLECULES, 2014, 47 (17) :5960-5970

[3]

Cochran E. W., 2013, Patent No. [US20130184383 A1, 20130184383]

[4]

Cochran E. W., 2014, Patent US, Patent No. [20140343192 Al, 20140343192]

[5] EPOXIDIZED TRIGLYCERIDES AS RENEWABLE MONOMERS IN PHOTOINITIATED CATIONIC POLYMERIZATION [J].

CRIVELLO, JV ;

NARAYAN, R .

CHEMISTRY OF MATERIALS, 1992, 4 (03) :692-699

[6]

D'Agosto Franck., 2008, Macromolecular Rapid Communications, V29, P934, DOI DOI 10.1002/MARC.200800209

[7] From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products [J].

Desroches, Myriam ;

Escouvois, Maxime ;

Auvergne, Remi ;

Caillol, Sylvain ;

Boutevin, Bernard .

POLYMER REVIEWS, 2012, 52 (01) :38-79

[8] Vegetable oil-based thermosetting polymers [J].

Galia, Marina ;

Montero de Espinosa, Lucas ;

Carles Ronda, Joan ;

Lligadas, Gerard ;

Cadiz, Virginia .

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY, 2010, 112 (01) :87-96

[9] Polyols and polyurethanes from hydroformylation of soybean oil [J].

Guo, A ;

Demydov, D ;

Zhang, W ;

Petrovic, ZS .

JOURNAL OF POLYMERS AND THE ENVIRONMENT, 2002, 10 (1-2) :49-52

[10] The battle for the "green" polymer. Different approaches for biopolymer synthesis: bioadvantaged vs. bioreplacement [J].

Hernandez, Nacu ;

Williams, R. Christopher ;

Cochran, Eric W. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2014, 12 (18) :2834-2849

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