Hydrogen Generation by Graphene Oxide-Alkylamine Hybrids through Photocatalytic Water Splitting

被引:16
作者
Ikeda, Yukino [1 ]
Karim, Mohammad Razaul [1 ,2 ]
Takehira, Hiroshi [1 ]
Hatakeyama, Kazuto [1 ]
Matsui, Takeshi [1 ]
Taniguchi, Takaaki [1 ,4 ]
Koinuma, Michio [1 ,4 ]
Matsumoto, Yasumichi [1 ,4 ]
Hayami, Shinya [1 ,3 ,4 ]
机构
[1] Kumamoto Univ, Grad Sch Sci & Technol, Chuo Ku, Kumamoto 8608555, Japan
[2] Shahjalal Univ Sci & Technol, Sch Phys Sci, Dept Chem, Sylhet 3114, Bangladesh
[3] Kumamoto Univ, Inst Pulsed Power Sci, Chuo Ku, Kumamoto 8608555, Japan
[4] CREST, JST, Chiyoda Ku, Tokyo 1020075, Japan
关键词
EFFICIENT; NITROGEN; CARBON; BORON; REDUCTION; OXIDATION; LIQUID;
D O I
10.1246/cl.131073
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the photocatalytic activities of graphene oxide alkylated amines (GO-A(n); GO: graphene oxide and A(n): alkylamine with n carbons in the alkyl group; n = 0, 1, 4, and 8). The hybrids were synthesized through facile, quick, and reproducible methods and were characterized by Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy, and powder X-ray diffraction (PXRD) analysis. The hybrids exhibited efficient photocataytic activity to generate hydrogen gas by water splitting under UV light irradiation at room temperature.
引用
收藏
页码:486 / 488
页数:3
相关论文
共 37 条
[1]  
Banhart F, 2011, ACS NANO, V5, P26, DOI [10.1021/nn102598m, 10.1016/B978-0-08-102053-1.00005-3]
[2]   Nitrogen-containing TiO2 photocatalysts -: Part 2.: Photocatalytic behavior under sunlight excitation [J].
Belver, C. ;
Bellod, R. ;
Stewart, S. J. ;
Requejo, F. G. ;
Fernandez-Garcia, M. .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 65 (3-4) :309-314
[3]   The electronic properties of graphene [J].
Castro Neto, A. H. ;
Guinea, F. ;
Peres, N. M. R. ;
Novoselov, K. S. ;
Geim, A. K. .
REVIEWS OF MODERN PHYSICS, 2009, 81 (01) :109-162
[4]   Edge-functionalized and substitutionally doped graphene nanoribbons:: Electronic and spin properties [J].
Cervantes-Sodi, F. ;
Csanyi, G. ;
Piscanec, S. ;
Ferrari, A. C. .
PHYSICAL REVIEW B, 2008, 77 (16)
[5]   One-pot reduction of graphene oxide at subzero temperatures [J].
Cui, Peng ;
Lee, Junghyun ;
Hwang, Eunhee ;
Lee, Hyoyoung .
CHEMICAL COMMUNICATIONS, 2011, 47 (45) :12370-12372
[6]   Functionalization of Graphene for Efficient Energy Conversion and Storage [J].
Dai, Liming .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (01) :31-42
[7]   Electronic and structural properties of two-dimensional carbon nitride graphenes [J].
Deifallah, Malek ;
McMillan, Paul F. ;
Cora, Furio .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (14) :5447-5453
[8]   Graphite oxide as a carbocatalyst for the preparation of fullerene-reinforced polyester and polyamide nanocomposites [J].
Dreyer, Daniel R. ;
Jarvis, Karalee A. ;
Ferreira, Paulo J. ;
Bielawski, Christopher W. .
POLYMER CHEMISTRY, 2012, 3 (03) :757-766
[9]   Preparation of Covalently Functionalized Graphene Using Residual Oxygen-Containing Functional Groups [J].
Hsiao, Min-Chien ;
Liao, Shu-Hang ;
Yen, Ming-Yu ;
Liu, Po-I ;
Pu, Nen-Wen ;
Wang, Chung-An ;
Ma, Chen-Chi M. .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (11) :3092-3099
[10]   Proton Conductivity of Graphene Oxide Hybrids with Covalently Functionalized Alkylamines [J].
Ikeda, Yukino ;
Karim, Mohammad Razaul ;
Takehira, Hiroshi ;
Matsui, Takeshi ;
Taniguchi, Takaaki ;
Koinuma, Michio ;
Matsumoto, Yasumichi ;
Hayami, Shinya .
CHEMISTRY LETTERS, 2013, 42 (11) :1412-1414