Study on the thermal stability and electrical properties of the high-k dielectrics (ZrO2) x (SiO2)1-x

被引:1
作者
Lue ShiCheng [1 ,2 ]
Yin Jiang [1 ,2 ]
Xia YiDong [2 ,3 ]
Gao LiGang [2 ,3 ]
Liu ZhiGuo [2 ,3 ]
机构
[1] Nanjing Univ, Dept Phys, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Natl Lab Solid State Microstruct, Nanjing 210093, Peoples R China
[3] Nanjing Univ, Dept Mat Sci & Engn, Nanjing 210093, Peoples R China
来源
SCIENCE IN CHINA SERIES E-TECHNOLOGICAL SCIENCES | 2009年 / 52卷 / 08期
关键词
high-k dielectric; film; pulsed laser deposition; pseudo ternary alloy; GATE DIELECTRICS; SILICON; FILMS;
D O I
10.1007/s11431-009-0226-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
(ZrO2) (x) (SiO2)(1-x) (Zr-Si-O) films with different compositions were deposited on p-Si(100) substrates by using pulsed laser deposition technique. X-ray photoelectron spectra (XPS) showed that these films remained amorphous after annealing at 800A degrees C with RTA process in N-2 for 60 s. The XPS spectra indicated that Zr-Si-O films with x=0.5 suffered no obvious phase separation after annealing at 800A degrees C, and no interface layer was formed between Zr-Si-O film and Si substrate. While Zr-Si-O films with x > 0.5 suffered phase separation to precipitate ZrO2 after annealing under the same condition, and SiO2 was formed at the interface. To get a good interface between Zr-Si-O films and Si substrate, Zr-Si-O films with bi-layer structure (ZrO2)(0.7)(SiO2)(0.3)/(ZrO2)(0.5)(SiO2)(0.5)/Si was deposited. The electrical properties showed that the bi-layer Zr-Si-O film is of the lowest equivalent oxide thickness and good interface with Si substrate.
引用
收藏
页码:2222 / 2226
页数:5
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