Characteristics of slag produced from incinerated hospital waste

被引:50
作者
Idris, A [1 ]
Saed, K [1 ]
机构
[1] Univ Putra Malaysia, Fac Engn, Dept Environm Chem & Engn, Waste Technol Ctr, Serdang 43400, Selangor, Malaysia
关键词
hospital waste; melting; slag; metals fractionation; metals leachability;
D O I
10.1016/S0304-3894(02)00010-9
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Ash produced from a hospital waste incinerator was treated using a high temperature melting process at 1200 degreesC. The quality of the produced slag was characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), leaching tests and sequential chemical extraction of metals. The slag contained large amounts Of SiO2, CaO, Al2O3, Sn, Ni, Cu, Ba and B. XRD analysis revealed a moderate crystal structure for the melted slag and identified the main crystals as quartz (SiO2), kaolinite (Al2Si2O5(OH)(4)), albite (NaAlSi3O8) and gibbsite (Al(OH)(3)). The observed crystal structure assists in preventing the leaching of heavy metals from the slag. Furthermore, the leaching results found the produced slag to comply with disposal lintits set by the US EPA. Results from sequential chemical extraction analysis showed that metals in the slag exhibited the strongest preference to be bound to the residual fraction (stable fraction), which is known to have very low leaching characteristics. Melting was found to stabilize heavy metals in hospital waste successfully and therefore it can be an acceptable method for disposal. (C) 2002 Elsevier Science B.V All rights reserved.
引用
收藏
页码:201 / 208
页数:8
相关论文
共 11 条
[1]  
Chermisinoff P.E., 1990, POLLUT ENG, V22, P60
[2]   CONTENT AND FRACTIONATION OF HEAVY-METALS IN WATER-TREATMENT SLUDGES [J].
ELLIOTT, HA ;
DEMPSEY, BA ;
MAILLE, PJ .
JOURNAL OF ENVIRONMENTAL QUALITY, 1990, 19 (02) :330-334
[3]   SPECIATION OF HEAVY-METALS IN SEWAGE-SLUDGE AND SLUDGE-AMENDED SOIL [J].
LEGRET, M .
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 1993, 51 (1-4) :161-165
[4]   Mechanical and leaching properties of cement solidified hospital solid waste incinerator fly ash [J].
Lombardi, F ;
Mangialardi, T ;
Piga, L ;
Sirini, P .
WASTE MANAGEMENT, 1998, 18 (02) :99-106
[5]   Melting and stone production using MSW incinerated ash [J].
Nishida, K ;
Nagayoshi, Y ;
Ota, H ;
Nagasawa, H .
WASTE MANAGEMENT, 2001, 21 (05) :443-449
[6]   SEQUENTIAL EXTRACTION PROCEDURE FOR THE SPECIATION OF PARTICULATE TRACE-METALS [J].
TESSIER, A ;
CAMPBELL, PGC ;
BISSON, M .
ANALYTICAL CHEMISTRY, 1979, 51 (07) :844-851
[7]  
*US EPA, 1982, SW846 US EPA
[8]  
*US EPA, 1982, 1310A US EPA
[9]  
*US EPA, 1992, METH DET MET ENV SAM, P123
[10]  
*US EPA, 1980, FED REG 261, V40, P24