Li3BS3 and LiSrBS3: New orthothioborates with trigonal planar boron coordination

被引：36
作者：
Hiltmann, F [1 ]
Jansen, C [1 ]
Krebs, B [1 ]
机构：
[1] UNIV MUNSTER,INST ANORGAN CHEM,D-48149 MUNSTER,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 09期
关键词：
orthothioborates; preparation; crystal structure;
D O I：
10.1002/zaac.19966220912
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report on the two new orthothioborates Li3BS3 (Pnma; a = 8.144(1) Angstrom, b = 10.063(2) Angstrom, 6.161(1) Angstrom; Z = 4) and LiSrBS3 (Pnma; a = 7.557(1) Angstrom, b = 9.083(2) Angstrom, c = 7.049(1) Angstrom; Z = 4). The two new phases were prepared by reaction of the metal sulfides, amorphous boron, and sulfur at 700 degrees C. Both compounds contain isolated, planar [BS3](3-) anions. The lithium ions have fourfold (Li3BS3 and sixfold (LiSrBS3) sulfur coordination, the strontium ion shows an eightfold sulfur coordination. The two compounds represent new A(3)BX(3) resp. AA'BX(3) structure types.
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页码：1508 / 1514
页数：7
相关论文
共 22 条
  • [1] LATTICE-VIBRATIONS OF BORON TRIHALIDE CRYSTALS
    BINBREK, OS
    KRISHNAMURTHY, N
    ANDERSON, A
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1974, 60 (11) : 4400 - 4405
  • [2] CHOPIN F, 1966, THESIS U BORDEAUX
  • [3] CRYSTAL-STRUCTURE OF B2S3 - 4-MEMBERED B2S2 RINGS AND 6-MEMBERED B3S3 RINGS
    DIERCKS, H
    KREBS, B
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1977, 16 (05): : 313 - 313
  • [4] Diercks H., 1977, ANGEW CHEM, V89, P327
  • [5] INFRARED SPECTRUM OF CRYSTALLINE BORON TRICHLORIDE
    DOWS, DA
    BOTTGER, G
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1961, 34 (02) : 689 - &
  • [6] EISENMANN B, 1983, REV CHIM MINER, V20, P255
  • [7] UNUSUAL LITHIUM DYNAMICS AND NMR RELAXATION IN A NOVEL CRYSTALLINE THIOBORATE-SULFIDE
    GRUNE, M
    MULLERWARMUTH, W
    ZUMHEBEL, P
    KREBS, B
    [J]. SOLID STATE IONICS, 1993, 66 (1-2) : 165 - 173
  • [8] SYNTHESIS AND STRUCTURE OF NA3B5O8S, THE 1ST OXOTHIOBORATE
    HAMMERSCHMIDT, A
    KREBS, B
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 183 : 393 - 402
  • [9] LIBABS3 AND LIBAB3S6 - 2 NEW QUATERNARY THIOBORATES WITH TRIGONALLY COORDINATED BORON
    HILTMANN, F
    KREBS, B
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (03): : 424 - 430
  • [10] LI5B7S13 AND LI9B19S33 - 2 LITHIUM THIOBORATES WITH NOVEL HIGHLY POLYMERIC ANION NETWORKS
    HILTMANN, F
    ZUMHEBEL, P
    HAMMERSCHMIDT, A
    KREBS, B
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1993, 619 (02): : 293 - 302
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