Synthesis and Deformable Hierarchical Nanostructure of Intrinsically Stretchable ABA Triblock Copolymer Composed of Poly(3-hexylthiophene) and Polyisobutylene Segments

被引：28

作者：

Higashihara, Tomoya ^{[1
]}

Fukuta, Seijiro ^{[1
]}

Ochiai, Yuto ^{[1
]}

Sekine, Tomohito ^{[1
]}

Chino, Keisuke ^{[2
]}

Koganezawa, Tomoyuki ^{[3
]}

Osaka, Itaru ^{[4
]}

机构：

[1] Yamagata Univ, Grad Sch Organ Mat Sci, Dept Organ Mat Sci, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan

[2] High Performance Mat Co, JXTG Oil & Energy Corp, HPM Res & Dev Dept, Chem R&D Grp,Naka Ku, 8 Chidoricho, Yokohama, Kanagawa 2310815, Japan

[3] Japan Synchrotron Radiat Res Inst, 1-1-1 Kouto, Sayo, Hyogo 6795198, Japan

[4] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, 1-4-1 Kagamiyama, Higashihiroshima, Hiroshima 7398527, Japan

来源：

ACS APPLIED POLYMER MATERIALS | 2019年 / 1卷 / 03期

基金：

日本学术振兴会;

关键词：

Nanostructure; block copolymer; poly(3-hexylthiophene); polyisobutylene; stretchable; self-assembly; LIVING CARBOCATIONIC POLYMERIZATION; CHAIN-GROWTH POLYMERIZATION; BLOCK-COPOLYMERS; DIBLOCK;

D O I：

10.1021/acsapm.8b00087

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A novel intrinsically stretchable ABA triblock copolymer can be synthesized where A and B are poly(3-hexylthiophene) (P3HT) and polyisobutylene (PIB) segments, respectively. The deformation of the self-assembled hierarchical nanostructure of the block copolymer thin film was clearly observed by grazing incidence small- and wide-angle X-ray scattering.

引用

页码：315 / 320

页数：11

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