Microporous Metal-Organic Frameworks for Gas Separation

被引:184
作者
Li, Bin [1 ]
Wang, Hailong [1 ]
Chen, Banglin [1 ]
机构
[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
关键词
gas separation; hydrogen; metal-organic frameworks; microporous materials; zeolites; CARBON-DIOXIDE CAPTURE; ZEOLITIC IMIDAZOLATE FRAMEWORKS; HIGHLY SELECTIVE SEPARATION; MOLECULAR-SIEVE MEMBRANE; COORDINATION-POLYMER; XYLENE ISOMERS; KINETIC SEPARATION; CO2; ADSORPTION; HIGH-CAPACITY; CU-BTC;
D O I
10.1002/asia.201400031
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microporous metal-organic frameworks (MOFs) are comparatively new porous materials. Because the pores within such MOFs can be readily tuned through the interplay of both metal-containing clusters and organic linkers to induce their size-selective sieving effects, while the pore surfaces can be straightforwardly functionalized to enforce their different interactions with gas molecules, MOF materials are very promising for gas separation. Furthermore, the high porosities of such materials can enable microporous MOFs with optimized gas separation selectivity and capacity to be targeted. This Focus Review highlights recent significant advances in microporous MOFs for gas separation.
引用
收藏
页码:1474 / 1498
页数:25
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