Branch Selective Mural-type Alkene Hydroarylation Reactions

被引：92

作者：

Crisenza, Giacomo E. M. ^{[1
]}

Bower, John F. ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMISTRY LETTERS | 2016年 / 45卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

C-H BOND; ASYMMETRIC INTERMOLECULAR HYDROARYLATION; REDUCTIVE ELIMINATION; BITE ANGLE; CROSS-COUPLINGS; DIRECT FUNCTIONALIZATION; NI-AL; ALKYLATION; ACTIVATION; SECONDARY;

D O I：

10.1246/cl.150913

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

There is significant interest in the development of C-C bond-forming methodologies that directly access challenging benzylic stereocenters. Predominantly, efforts have been focused on the development of enantiospecific or enantioselective cross-coupling methodologies. An alternate and conceptually ideal approach involves the development of branch-selective and enantioselective Murai-type alkene hydroarylations. Recent progress towards this broad, yet challenging goal is highlighted.

引用

页码：2 / 9

页数：8

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