Inhomogeneous mode-coupling theory and growing dynamic length in supercooled liquids

被引:257
作者
Biroli, Giulio [1 ]
Bouchaud, Jean-Philippe
Miyazaki, Kunimasa
Reichman, David R.
机构
[1] Orme Merisiers CEA Saclay, Serv Phys Theor, F-91191 Gif Sur Yvette, France
[2] Orme Merisiers CEA Saclay, Serv Phys Etat Condense, F-91191 Gif Sur Yvette, France
[3] Capital Fund Management, F-75009 Paris, France
[4] Columbia Univ, Dept Chem, New York, NY 10027 USA
关键词
D O I
10.1103/PhysRevLett.97.195701
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We extend mode-coupling theory (MCT) to inhomogeneous situations, relevant for supercooled liquid in an external field. We compute the response of the dynamical structure factor to a static inhomogeneous external potential and provide the first direct evidence that the standard formulation of MCT is associated with a diverging length scale. We find that the so-called cages are, in fact, extended objects. Although close to the transition the dynamic length grows as vertical bar T-T-c vertical bar(-1/4) in both the beta and alpha regimes, our results suggest that the fractal dimension of correlated clusters is larger in the alpha regime. We derive inhomogeneous MCT equations valid to second order in gradients.
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页数:4
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