Discussion on the structure of boron containing apatite

被引：4

作者：

Baykal, A ^{[1
]}

Gürbüz, G

Kizilyalli, M

Kniep, R

机构：

[1] Fatih Univ, Dept Chem, Istanbul, Turkey

[2] Cimento Mustahsilleri Birligi, Ankara, Turkey

[3] Middle E Tech Univ, Dept Chem, TR-06531 Ankara, Turkey

[4] Max Planck Inst Chem Phys Fester Stoffe, VEM Sachsenwerk, D-0125 Dresden, Germany

来源：

EURO CERAMICS VIII, PTS 1-3 | 2004年 / 264-268卷

关键词：

apatite; boron apatite; X-ray diffraction; FTIR analysis; solid state synthesis;

D O I：

10.4028/www.scientific.net/KEM.264-268.2017

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The single crystals of boron containing apatite (BAP) with the formula Ca9.93B0.93P5.84O25.79 has been grown using flux method and characterised before. On the other hand a structure resembling BAP has been observed during the synthesis and investigation of the melting behaviour of Ca3BPO7 in our work. Upon heating at 1440 degreesC and cooling, colorless crystals were obtained. The structure was found to be trigonal with the space group P3(-) and z = 1.The unit cell parameters are a = 9.275 (6), c = 6.952 (2) Angstrom which are in close aggreement with the reported Sr Na BAP compound. Ca BAP was also obtained in the powder form using three different solid state reactions and the x- ray powder diffraction pattern was indexed with the unit cell parameters of a = 9.455 (6) and c = 6.905 ( 2) which were the same as the literature data of Ca BAP of trigonal structure with the space group PY and z = 1. The IR data agreed with reported values

引用

页码：2017 / 2021

页数：5

共 13 条

[1] EFFECTS OF ELECTRIC CURRENTS ON BONE IN VIVO [J].

BASSETT, CA ;

PAWLUK, RJ ;

BECKER, RO .

NATURE, 1964, 204 (495) :652-&

[2]

BAUR WH, 1973, AM CRYS ASS SUMM M U

[3]

BAYKAL H, 1998, THESIS MIDDLE E TU A

[4]

CALVO C, 1975, ACTA CRYSTALLOGR B, V3, P188

[5]

GOZEL G, 1993, THESIS MIDDLE E TU A

[6]

ITO A, 1988, J CERAM SOC JPN, V96, P302

[7]

ITO A, 1988, J CERAM SOC JPN, V96, P695

[8] BOROPHOSPHATES - A NEGLECTED CLASS OF COMPOUNDS - CRYSTAL-STRUCTURES OF M(II)[BPO5] (M(II)=CA, SR) AND BA-3[BP3O12] [J].

KNIEP, R ;

GOZEL, G ;

EISENMANN, B ;

ROHR, C ;

ASBRAND, M ;

KIZILYALLI, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07) :749-751

[9]

LEGEROS RZ, 1991, ORAL BIOL MED

[10] A new method for the solid-state synthesis of tetracalcium phosphate, a dental cement: X-ray powder diffraction and IR studies [J].

Sargin, Y ;

Kizilyalli, M ;

Telli, C ;

Guler, H .

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1997, 17 (07) :963-970

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