SYNTHESIS OF A HYPERBRANCHED POLY(AROYLARYLENE) CONTAINING TRIAZOLE AND FLUORENE FUNCTIONALITIES BY CLICK CHEMISTRY AND METAL-FREE, REGIOSELECTIVE POLYCYCLOTRIMERIZATION

被引：12

作者：

Qin, An-jun ^{[1
,2
]}

Jim, Cathy K. W. ^{[2
]}

Lam, Jacky W. Y. ^{[2
]}

Sun, Jing-zhi ^{[1
]}

Tang, Ben Zhong ^{[1
,2
]}

机构：

[1] Zhejiang Univ, Minist Educ, Key Lab Macromol Synth & Functionalizat, Dept Polymer Sci & Engn, Hangzhou 310027, Peoples R China

[2] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

CHINESE JOURNAL OF POLYMER SCIENCE | 2009年 / 27卷 / 02期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

Regioregular; Click chemistry; Polycyclotrimerization; Hyperbranched polymer; POLYMERS; POLYTRIAZOLES;

D O I：

10.1142/S0256767909003765

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new bis(aroylacetylene) containing triazole and fluorene moieties is synthesized by click chemistry. Polycyclotrimerization of the monomer is catalyzed by piperidine in refluxed dioxane, furnishing a regioregular poly(aroylarylene) in a satisfactory yield. The hyperbranched structure of the polymer is characterized spectroscopically with satisfactory results. The polymer enjoys no metal detriment and is soluble in common organic solvents such as tetrahydrofuran (THF), chloroform, dichloromethane (DCM), and N,N-dimethylformamide (DMF).

引用

页码：145 / 148

页数：4