Complex permittivity analysis revisited: Microwave spectroscopy of organic semiconductors with resonant cavity

被引:24
作者
Choi, Wookjin [1 ]
Tsutsui, Yusuke [1 ]
Sakurai, Tsuneaki [1 ]
Seki, Shu [1 ]
机构
[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Kyoto 6158510, Japan
基金
日本学术振兴会;
关键词
TRAPPED ELECTRONS; HIGH-PERFORMANCE; CONDUCTIVITY; TRANSISTORS; STATES; FREQUENCY; MOBILITY;
D O I
10.1063/1.4980078
中图分类号
O59 [应用物理学];
学科分类号
摘要
The complex permittivity analysis of microwave dielectric loss spectroscopy has been revisited to deduce the intrinsic values of the mobility of charge carriers injected at the interface between an organic semiconductor and a gate insulator. A perturbation model with a simple parabolic function for frequency-dependent microwave resonance in the cavity enables us to experimentally determine the real and imaginary parts of the permittivity change caused by the injected charge carriers based on the Drude-Zener model, leading to the simultaneous assessment of the intrinsic charge-carrier mobility, the averaged trap depth/density, and the ratio of free-trapped charge carriers. The present frequency-dependent precise analysis of complex permittivity provides rapid and non-destructive screening of the total landscape of the charge-carrier transport at interfaces. Published by AIP Publishing.
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页数:5
相关论文
共 32 条
[1]   PHOTODIELECTRIC DETECTOR USING A SUPERCONDUCTING CAVITY [J].
ARNDT, GD ;
HARTWIG, WH ;
STONE, JL .
JOURNAL OF APPLIED PHYSICS, 1968, 39 (06) :2653-&
[2]   Accuracy of microwave cavity perturbation measurements [J].
Carter, RG .
IEEE TRANSACTIONS ON MICROWAVE THEORY AND TECHNIQUES, 2001, 49 (05) :918-923
[3]   Non-contact, non-destructive, quantitative probing of interfacial trap sites for charge carrier transport at semiconductor-insulator boundary [J].
Choi, Wookjin ;
Miyakai, Tomoyo ;
Sakurai, Tsuneaki ;
Saeki, Akinori ;
Yokoyama, Masaaki ;
Seki, Shu .
APPLIED PHYSICS LETTERS, 2014, 105 (03)
[4]   DIELECTRIC MEASUREMENTS ON SUBSTRATE MATERIALS AT MICROWAVE-FREQUENCIES USING A CAVITY PERTURBATION TECHNIQUE [J].
DUBE, DC ;
LANAGAN, MT ;
KIM, JH ;
JANG, SJ .
JOURNAL OF APPLIED PHYSICS, 1988, 63 (07) :2466-2468
[5]   In Situ Detection of Free and Trapped Electrons in Dye-Sensitized Solar Cells by Photo-Induced Microwave Reflectance Measurements [J].
Dunn, Halina K. ;
Peter, Laurence M. ;
Bingham, Stephen J. ;
Maluta, Eric ;
Walker, Alison B. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (41) :22063-22072
[6]   Highly soluble [1]benzothieno[3,2-b]benzothiophene (BTBT) derivatives for high-performance, solution-processed organic field-effect transistors [J].
Ebata, Hideaki ;
Izawa, Takafumi ;
Miyazaki, Eigo ;
Takimiya, Kazuo ;
Ikeda, Masaaki ;
Kuwabara, Hirokazu ;
Yui, Tatsuto .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (51) :15732-+
[7]   Microwave response due to light-induced changes in the complex dielectric constant of semiconductors [J].
Grabtchak, S ;
Cocivera, M .
PHYSICAL REVIEW B, 1998, 58 (08) :4701-4707
[8]   Behavior of photoconductivity transients due to multiple trapping by a Gaussian distribution of localized states [J].
Grabtchak, S ;
Cocivera, M .
PHYSICAL REVIEW B, 1999, 60 (15) :10997-11004
[9]   Interpreting transient photocurrents as a signature of the density of states distribution: the profound importance of the short-time decay [J].
Grabtchak, S ;
Main, C ;
Reynolds, S .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 266 :362-366
[10]   Evaluation of Intrinsic Charge Carrier Transport at Insulator-Semiconductor Interfaces Probed by a Non-Contact Microwave-Based Technique [J].
Honsho, Yoshihito ;
Miyakai, Tomoyo ;
Sakurai, Tsuneaki ;
Saeki, Akinori ;
Seki, Shu .
SCIENTIFIC REPORTS, 2013, 3