New Research Developments on Acrylamide: Analytical Chemistry, Formation Mechanism, and Mitigation Recipes

被引:96
作者
Zhang, Yu [1 ]
Ren, Yiping [2 ]
Zhang, Ying [1 ]
机构
[1] Zhejiang Univ, Sch Biosyst Engn & Food Sci, Dept Food Sci & Nutr, Hangzhou 310029, Zhejiang, Peoples R China
[2] Zhejiang Prov Ctr Dis Control & Prevent, Hangzhou 310051, Zhejiang, Peoples R China
关键词
TANDEM MASS-SPECTROMETRY; CEREAL-BASED FOODS; FREE AMINO-ACIDS; PRESSURIZED FLUID EXTRACTION; FRIED POTATO PRODUCTS; MU-G/KG ACRYLAMIDE; LIQUID-CHROMATOGRAPHY; GAS-CHROMATOGRAPHY; MAILLARD REACTION; MODEL SYSTEM;
D O I
10.1021/cr800318s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
New research developments on acrylamide with reference to analytical chemistry, formation mechanism and a mitigation recipe have been demonstrated. Acrylamide is a colorless and odorless crystalline powder and is soluble in water, acetone, and ethanol. The new analytical methods include capillary zone electrophoresis, liquid chromatography with pulsed electrochemical detection, and time-of-flight mass spectrometry. Mechanistic study reveals that three products including maleimide, succinimide, and niacinamide may be generated besides the formation of acrylamide during the asparagine pathway. Special focus is concerned about the formation and impact factors of acrylamide in potato-based products, bakery products, cereal, coffee, almonds, and olives. A mechanistic study is needed to clarify the key functional groups of the additives which play an important role in the mitigation process.
引用
收藏
页码:4375 / 4397
页数:23
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