Layer-by-Layer Liquid-Phase Epitaxy of Crystalline Coordination Polymers at Surfaces

被引：44

作者：

Fischer, Roland A. ^{[1
]}

Woell, Christof ^{[1
]}

机构：

[1] Ruhr Univ Bochum, D-44780 Bochum, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 34期

关键词：

coordination modes; coordination polymers; layer-by-layer techniques; metal-organic frameworks; surface chemistry; METAL-ORGANIC FRAMEWORKS; CATIONIC BIPOLAR AMPHIPHILES; ULTRATHIN MULTILAYER FILMS; SELF-ASSEMBLY PROCESS; CONSECUTIVE ADSORPTION; CHARGED SURFACES; COMPLEXES; DESIGN; NETS; CONSTRUCTION;

D O I：

10.1002/anie.200901090

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Topping it off: Layer-by-layer growth was used to produce a highly oriented crystalline surface coordination polymer made up of copper dithiooxamide complexes (see scheme; SAM=selfassembled monolayer). This example demonstrates that layer-by-layer growth in the liquid phase can produce a highly crystalline system even in difficult cases. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

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收藏

页码：6205 / 6208

页数：4

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